Lecture Notes on Metamorphism (Dr. Hogan's Lectures Only)
Part I
Metamorphism: mineralogical and/or textural change brought about
in a rock in the solid state as a result of increase in temperature
and pressure.
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need to consider the initial and final states of equilibrium - the phase
rule can be applied to assess the approach of the mineral assemblage to
equilibrium
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need to consider which chemical and/or physical variables must change,
and how, to provide a driving force for reequilbration of the mineral assemblage.
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Pressure
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Temperature
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P and T are interdependent and define a "geothermal gradient"
Local P-T gradients can vary significantly depending on tectonic environments:
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anomalously high temperatures at shallow depths through heat input accompanying
intrusion of magma.
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anomalously low temperatures at deep crustal levels associated with subduction
of cold dense oceanic lithosphere.
Other variables are also significant:
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Partial pressure of H2O and CO2
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Internally controlled by reactions involving the thermal decomposition
of hydrous and/or carbonate minerals.
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externally controlled by movement of fluid from a reservoir outside the
system through the rock in large quantities.
Question: Is fluid flow pervasive (i.e., moving throughout
the rock along grain boundaries) or focussed (i.e., fluid flow is
controlled by the presence of fractures, bedding planes, etc.)?
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What is the significance of these models?
The presence of a fluid phase acts as a catalyst promoting diffusion and
enabling reactions to progress.
Regional Metamorphism
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covers 100's to 1000's of km2
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involves temperatures above normal geothermal gradient (High P -
Low T metamorphism is considered separately).
Some consider any metamorphism where there is not a readily identifiable
local heat source regional metamorphism.
"Process" oriented petrologists recognize considerable overlap between
contact and regional metamorphic processes, and recognize that elevated
geothermal gradients indicated by regional metamorphism commonly require
heat input from igneous intrusions and associated magmatic fluids.
This really shouldn't be so surprising as physical chemical thermodynamic
principles predict rocks of similar composition metamorphosed to the same
P-T conditions should show similar mineralogical changes regardless of
the source of heat.
Metamorphic Textures / Structures
Any rock can undergo metamorphism. Thus, metamorphic rocks are compositionally,
mineralogical, and texturally diverse.
Metamorphism and deformation commonly occur synchronously. Many combinations
of heating rates and strain rates are possible.
Static metamorphism (increasing T) produces coarser grained minerals
whereas deformation processes serve to reduce mineral size and impart a
fabric (i.e., foliation and/or lineation) to the rock. The integrated
effects of these two processes dictate the final appearance of the metamorphic
rock.
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Textures of metamorphic rocks range from massive to foliated.
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Grain Sizes range from extremely fine to very coarse.
Recrystallization/Mineral Growth
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metamorphic minerals are called "blasts".
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Porphyroblast: metamorphic minerals that are much larger than the surrounding
matrix (e.g., garnet porphyroblasts).
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Granoblastic: a metamorphic rock comprised of equigranular crystals.
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Poikiloblast: porphyroblasts which contain numerous small inclusions of
matrix minerals.
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Pseudemorph: replacement of a previous mineral by new, smaller metamorphic
minerals whic retain the crystal form of the previous mineral.
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Idioblastic: well formed crystals.
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hypidoblastic: medium crystal development.
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xenoblastic: anhedral crystals.
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Increasing T cause an increase in grain size (in the absence of shear stress)
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annealing: increase in average grain size and formation of a polygonal
texture (5-6 sided grains sharing 120o "triple junction" grain
boundaries.
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energy reduction process which serves to minimize the energy of the system
and achieve textural equilibrium
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Final texture will be related to the types and proportions of minerals
and the rates at which they grow (surface area).
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one large crystal has less surface area than a bunch of smaller crystals
of equivalent mass. Thus a rock a constant P-T conditions can lower its
total energy by simply growing coarser crystals!
Effects of Deformation
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Grain size reduction (communition)
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dynamic recrystallization
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dislocation creep
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grain boundary migration
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fracturing
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Development of planar structures
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slaty cleavage
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phyllitic cleavage
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crenulation cleavage
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schistosity
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gneissic fabric
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mylonites
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tectonites
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Development of linear structures
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mineral lineation
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rodding
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crenulation lineation
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intersection lineation
Nomenclature of Metamorphic Rocks (see handout using mudrocks as
an example)
Based on mineralogy, texture, and structure. Widely used rock names
(e.g., schist, gneiss) modified by a textural term (e.g., augen, mylonitic)
or the presence of key minerals (e.g., garnet, biotite). Rocks that are
predominantly monomineralic are named for the dominant mineral (e.g.,
quartzite, serpentinite).
The majority of metamorphic rocks fall into three categories (broadly
speaking) based on protolith composition.
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Aluminous clastic sedimentary rocks (mudrocks, pelites, greywackes, dirty
sandstones etc.)
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Calcareous rocks (limestones, dolomites, marls)
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typically granoblastic marbles dominated by calcite and dolomite
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non-carbonate minerals include
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low metamorphic grade: phlogopite and tremolite
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higher metamorphic grade: diopside, wollastonite, calcic plagioclase, grossular,
forsterite
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Calcsilicate rocks (dirty carbonates (marls) containing abundant detrital
silicate minerals)
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follow a similar textural development to mud rocks (see handout)
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low grade: chlorite, epidote, actinolite
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higher grade: augite, hornblende, calci plagioclase, garnet.
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at very high grades can resemble amphibolites (metamorphosed basalts).
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Mafic to intermediate volcanic rocks (basalts, andesites, dacites, flows
and pyroclastics)
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low grade "greenstones" greenschist facies due to the inherently greenish
color of the metamorphic minerals which develop (chlorite, actinolite,
epidote, Na-plagioclase)
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higher grade "amphibolites" dominated by hornblende and plagioclase
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highest grade "eclogite" dominated by opx, cpx, garnet, calcic plagioclase,
and olivine.