1. Ideal Gas Law


    P is the pressure
    V is the volume
    n is the amount of gas
    R is the Real Gas constant, with units appropriate for the units of pressure, volume, temperature, and amount of gas.
    T is the temperature (in Kelvin because an absolute scale is necessary.)
    Noggle- 3
  2. The Van Der Waals Equation


    The constant a accounts for the attractive forces between gas molecules; PV=nRT assumed there were no attractions whatsoever.
    The constant b accounts for the volume taken up by the gases; PV=nRT assumed gases to be points of infinitismally small volume.
    V(m) is volume divided by amount in moles
    Noggle- 5
  3. The Root Mean Square Speed of a Gas


    u is the root-mean-square speed
    R is the Real Gas constant, with units appropriate for the units of pressure, volume, temperature, and amount of gas.
    T is the temperature M is the molar mass
    Noggle- 32
  4. The Coefficient of Thermal Expansion


    alpha is the coefficient of thermal expansion
    V is the volume
    delta V is the change in volume
    delta T is the change in temperature P is the pressure and it is held constant
    Noggle- 59
  5. The Isothermal Compressibility


    kappa(T) is the isothermal compressibility
    V is the volume
    delta V is the change in volume
    delta P is the change in pressure
    T is the temperature, and it is held constant.
    Noggle- 71
  6. Heat Capacity at Constant Volume


    C(v) is the heat capacity at constant volume
    q is the quantity of heat given off
    T is the temperature
    V is the volume
    Noggle- 71
  7. Molar Heat Capacity


    C(vm) is the molar heat capacity (constant volume)
    n is moles
    Noggle- 72
  8. Work of Pressure


    F is force
    x is a one dimensional coordinate
    A is area
    V is volume
    P(ex) is the pressure which opposes expansion
    Noggle- 81
  9. Heat Capacity


    C(p) is Heat Capacity at Constant Pressure
    H is enthalpy
    P is pressure
    U is internal energy
    V is volume
    T is the temperature
    Noggle- 86
  10. Entropy of Mixing for Two Gases


    Delta (mix) S is the entropy of mixing for two gases
    n is moles
    R is the real gas constant
    X is the mole fraction of the gas
    Noggle- 136

  11. Joule-Thompson Coefficient


    mu is the Joule Thompson coefficient
    H is the enthalpy
    P is the preaasure
    T is the temperature
    Noggle- 109

  12. Equation for Entropy, Heat, and Temperature


    rev indicates the equation is valid only for a reversible process
    q is the heat
    S is the entropy
    T is the temperature
    Noggle- 128
  13. Equation 13 was a repeat of 10- This space available for a different equation.
  14. Clapeyron Equation


    Delta phi X is the heat required at constant pressure and constant temperature, to effect a phase change
    P is pressure
    T is temperature
    Delta phi V is the change in molar volume
    Noggle- 175
  15. 2

  16. Change in Enthalpy with Temperature and Change in Heat Capacity with Temperature


    Delta (rxn) H(T) is the change in the enthalpy of a reaction at a specified temperature
    Cp is the heat capacity at a constant pressure
    T is the temperature
    Noggle- 280
  17. Law of Mass Action(the reaction equality is the Van't Hoff Equation)


    Small case variables (a,b,c,d) are stoichiometric coefficients
    Large case variables (A,B,C,D) are chemical species
    C and D are products, and A and B are reactants
    K(a) is the thermodynamic equilibrium constant
    Notice that what involves addition and subtraction in one equation relates to multiplication and division in the other
    Noggle- 286
  18. K(a) is the thermodynamic equilibrium constant


    Delta(f)G phi is the standard free energy of formation
    K(a) is the thermodynamic equilibrium constant
    R is the Real Gas constant
    T is temperature
    Noggle- 291
  19. Enthalpy, Free Energy, and Temperature at Constant Pressure


    G is Free Energy
    H is enthalpy
    P is pressure
    T is temperature
    Noggle- 295
  20. Thermodynamic Equilibrium, Enthalpy, and Temperature


    Delta(rxn)H(phi) is the change in enthalpy from the reaction
    K(a) is thermodynamic equilibrium
    T is temperature
    Noggle- 298
  21. Gibbs' Phase Rule


    c is the number of components (I think this means c different 'types' of components--hey, components is a nebulous word, so I'll try to find an example of what it means
    F is the degrees of freedom
    p is the number of phases
    Noggle- 339
  22. Gibbs-Duhem Equation


    d mu is the change in chemical potential
    n is the number of moles
    Noggle- 356
  23. Reduced Mass


    mu is the reduced mass
    m is the mass of one of the two objects
    Noggle- 1057
  24. 11 was a repeat--PChem24.gif is available for a new equation
  25. Half Life Equation


    t is time
    k is the "half life constant" (no specific name found)
    Noggle- 521
  26. Arrhenius Activation Energy Equation


    E(a) is the Arrhenius activation energy
    k is the "rate constant" (no specific name found)
    R is the Real Gas constant T is the temperature Noggle- 528
  27. The Integrated form of the
    Arrhenius Activation Energy Equation


    E(a) is the Arrhenius activation energy
    k is the "rate constant" (no specific name found)
    R is the Real Gas constant
    T is the temperature
    Noggle- 528
  28. Arrhenius Equation Solved for k


    E(a) is the Arrhenius activation energy
    k is the "rate constant" (no specific name found)
    R is the Real Gas constant
    T is the temperature
    Noggle- 529
  29. A repeat of an equation
    PChem29.gif is now available for a new equation


  30. Michaelis-Menton Equation


    v is the velocity of the overall (biochemical) reaction
    v(max) is the maximum velocity the reaction could achieve
    K(m) is the Michaelis constant
    [S] is the substrate concentration
    Noggle- 582
  31. DeBroglie Equation


    Lambda is wavelength of the object
    h is Planck's constant
    m is the mass of the object
    v is the velocity of the object
    Noggle- 614
  32. Definition of the Commutator


    x and d are operators, as signified by the "carrot" symbol
    f(x) is a generic function
    [d,x] represents the commutator of variables d and x
    Noggle- 618
Last Update- December 19, 1994- wld