Zn(s)  +  2 HCl(aq) ---->  ZnCl2(aq)  +  H2(g)

2 Al(s)  +  6 HCl(aq) ---->  2 AlCl3(aq)  +  3 H2(g)

Cu(s)  +  n HCl(aq)  --x-->  no reaction

Note:  Cu is below H (0.00 V ref) in table, so
It will not react with acids H+(aq) to form H2(g)
Metals above H in the table will react with acids.
Other Reactions in the Procedure:
 Removal of Excess Reducing Agent