The iron (III) ion also introduces a complication because of its reaction with water to form iron hydroxide, which is insoluble in water:

Fe3+ (aq) + 3 H2O (l) <==> Fe(OH)3 (s) + 3 H+ (aq)
To avoid precipitation of iron (III) hydroxide, you will include excess nitric acid (HNO3) in all solutions, to shift this equilibrium far to the left.

Because neither hydrogen ions nor nitrate ions are components of the iron (III) thiocyanate equilibrium, nitric acid does NOT affect the equilibrium position
of the reaction that produces FeSCN2+.
In TodayÕs Experiment