Publications

100.  R. K. Brow, M. Karabulut, E. Metwalli, A. Wittenauer, K. Marasinghe C.H. Booth, J.J. Bucher & D.K. Shuh,
        “The Structure of Rare Earth Phosphate Glasses,” Extended Abstract, 19th ICG, Edinburgh, Scotland, July 1-7, 2001.

99.    U. Hoppe, E. Metwalli, R. K. Brow, and J. Neuefeind, “High-energy X-ray diffraction study of La-coordination in
        lanthanum phosphate glasses,” J. Non-Cryst. Solids, (submitted, 7/01)

98.   M. Karabulut, G.K. Marasinghe, E. Metwalli, A. K. Wittenauer, R.K. Brow, C.H. Booth, J.J. Bucher, and
        D.K. Shuh, “Neodymium and erbium coordination environments in phosphate glass,” (submitted to Phys. Rev. B, 5/01).

97.   E. Metwalli and R. K. Brow, “Modifier effects on the properties and structures of aluminophosphate glasses,”
        J. Non-Cryst. Solids, (accepted, 4/01).

96.   M. Karabulut, G. K. Marasinghe, C. A. Click, E. Metwalli, R. K. Brow, C. H. Booth, J. J. Bucher, D. K. Shuh, T. I.
        Suratwala and J. H. Campbell, “An XAFS investigation of platinum local environment in phosphate laser glasses,”
        J. Amer. Ceram. Soc. (accepted, 7/01).

95.   M. Karabulut, E. Metawalli, and R. K. Brow, “Properties and Structure of Lanthanum Aluminophosphate Glasses,”
        J. Non-Cryst. Solids, 283, 211-219 (2001)..

94.    E. Metwalli, R. K. Brow, and F. S. Stover, “Cation effects on anion distributions in aluminophosphate glasses,”
        J. Amer. Ceram. Soc., 84[5] 1025-32 (2001)..

93.   R. K. Brow, E. Metawalli, and D. L. Sidebottom, “Properties and Structure of Lanthanum Phosphate Glasses,” in
        Inorganic Optical Materials for Visible and Infrared Applications, Proceedings of the International 45th Annual
        Meeting of the SPIE, San Diego, July 2000, Vol. 4102, 88-94 (2000)..

92.   R. K. Brow, C. A. Click, and T. M. Alam, "Modifier Coordination and Phosphate Glass Networks,"  J. Non-Cryst.
        Solids 274, 9-16 (2000).

91.   T. M. Alam, J. McLaughlin, C. Click, S. Conzone, R. K. Brow, T. J. Boyle and J. Zwanziger, "Sodium Distributions in
        Phosphate Glasses Probed With Spin-Echo 23Na NMR," J. Phys. Chemistry B, 104[7] 1464-1472 (2000).

90.   P. F. Green, E. F. Brown, and R. K. Brow, "Linear Viscoelasticity of an Ultraphosphate Glass," J. Non-Cryst. Solids
        263/264 195-201 (2000).

89.   R. K. Brow, "Review: The Structure of Simple Phosphate Glasses," J. Non-Cryst. Solids, 263/264 1-28 (2000).

88.    T. M. Alam, S. Conzone, T. J. Boyle, R. K. Brow, "6Li, 7Li nuclear magnetic resonance investigation of alkali
         coordination in lithium ultraphosphate glasses," Journal of Non-Crystalline Solids, 258 140-154 (1999).

87.   P. F. Green, E. F. Brown, and R. K. Brow, "Dynamics of Mixed Alkali Metaphosphates Glasses and Melts,"
       Journal of Non-Crystalline Solids, 255[1], 87-96 (1999).

86.    D. L. Sidebottom, P. F. Green, and R. K. Brow, "Brillouin scattering in alkali metaphosphate glasses and
        melts," Journal of Molecular Structure, 479 219-226 (1999).

85.    R. K. Brow, T. M. Alam, D. R. Tallant, and R. J. Kirkpatrick, "Spectroscopic Studies on the Structures of Phosphate
        Sealing Glasses," MRS Bulletin 23[11] 63-67 (1998).

84.    P. F. Green, R. K. Brow, and J. J. Hudgens, "Specific heat and transport "anomalies" in mixed alkali glasses," J. Chem.
         Physics, 109[18] 7907-7912 (1998).

83.    P. F. Green, D. L. Sidebottom, R. K. Brow, and J. J. Hudgens, "Mechanical Relaxation Anomalies in Mixed Alkali
        Oxides," J. Non. Cryst. Solids, 231 89-98 (1998).

82.    S. K Saha, H. Jain, J. I. Goldstein, A. C. Miller and R. K. Brow, "Reaction Between Titanium And B2O3 Melt/Glass",
        Physics & Chemistry of Glasses, 39(2) 118-121 (1998).

81.    T. M. Alam and R. K. Brow, “NMR Studies of Bond Arrangements in Alkali Phosphate Glasses” Proceedings of
        the 18th International Congress on Glass, San Francisco, CA July 5-10, 1998.

80.    D. L. Sidebottom, P. F. Green, and R. K. Brow, “Regarding the Correlation of Nuclear Spin Relaxation and Electrical
        Conductivity Relaxation in Ionic Glasses,” Journal of Chemical Physics, 108(14):5870-5875 (1998).

79.    J. J. Hudgens, R. K. Brow, D. R. Tallant, and S.W. Martin, "Raman Spectroscopy Study of the Structure of Lithium
         and Sodium Ultraphosphate Glasses," J. Non. Cryst. Solids, 223[1,2] 21-31 (1998).

78.    T. M. Alam and R. K. Brow, "Local structure and connectivity in lithium phosphate glasses: a solid-state 31P MASNMR
        and 2D exchange investigation," J. Non. Cryst. Solids, 223[1,2] 1-20 (1998).

77.    R. K. Brow, D. N. Bencoe, L. Kovacic, and D. R. Tallant, "PbO-Free Materials for Low Temperature Packaging,"
        Sandia Report SAND97-2391, Printed October 1997.

76.    D. L. Sidebottom, M. A. Hruschka, B. G. Potter, and R. K. Brow, "Increased Radiative Lifetime of Rare Earth-Doped
        Zinc Oxyhalide Tellurite Glasses," Appl. Phys. Lett. 71[14] 1963-65 (1997).

75.    R. K. Brow and D. R. Tallant, "Structural Design of Sealing Glasses," J. Non. Cryst. Solids, 222 396-406 (1997).

74.    D. L. Sidebottom, P. F. Green, and R. K. Brow, "Structural Correlations in the AC Conductivity of Ion Containing
        Glasses," J. Non. Cryst. Solids, 222 354-360 (1997).

73.    D. L. Sidebottom, M. A. Hruschka, B. G. Potter, and R. K. Brow, "Structure And Optical Properties Of Rare
        Earth-Doped Zinc Oxyhalide Tellurite Glasses,"  J. Non. Cryst. Solids, 222 282-289 (1997).

72.    R. K. Brow, D. R. Tallant, W. L. Warren, A. McIntyre and D. E. Day, "Spectroscopic Studies of the Structure of
        Titanophosphate and Calcium Titanophosphate Glasses," Phys. Chem. Glasses, 38[6], 300-306 (1997).

71.    D. L. Sidebottom, M. A. Hruschka, B. G. Potter, R. K. Brow, and J. J. Hudgens, "Optical Properties of
        Lanthanide-Containing Halide-Modified Zinc Tellurite Glasses," Mat. Res. Soc. Symp. Proc., 453 253-258 (1997).

70.    X. Yu, D. E. Day, G. L. Long, and R. K. Brow, "Structure and Properties of Sodium-Iron-Phosphate Glasses," J.
        Non-Cryst. Solids215[1], 21-31 (1997).

69.    R. K. Brow, D. R. Tallant, and G. L. Turner, "Polyhedral Arrangements in Lanthanum Aluminoborate Glasses,"
        J. Amer. Ceram. Society, 80[5] 1239-1244 (1997).

68.    D. L. Sidebottom, P. F. Green, and R. K. Brow, "Scaling Parallels in the Non-Debye Behavior of Ionic and Dipolar
        Supercooled Liquids," Phys. Rev. B, 56 170 (1997).

67.    R. K. Brow, "Spectroscopic Studies of Glass Structure, " Proceedings of the Norbert Kreidl Symposium, Glastech.
        Ber., 70C 55-62 (1997).

66.    R. K. Brow, D. R. Tallant, S. V. Crowder, S. K. Saha, H. Jain, A. McIntyre, and D. E. Day, "Advanced Materials for
        Aerospace and Biomedical Applications: New Glasses for Hermetic Titanium Seals," Sandia Report, SAND 96-2772,
        Nov. 1996.

65.    R. K. Brow, "Precollege Science Education: Start Them Early," Bulletin of the American Ceramic Society, 75[4]
        69-70 (1996).

64.    D. L. Sidebottom, P. F. Green, and R. K. Brow, "Scaling Behavior in the Conductivity of Alkali Oxide Glasses,
        Polymers, and Doped Crystals," J. Non-Crystalline Solids, 203, 300-305 (1996).

63.    S. K. Saha, H. Jain. A. C. Miller, and R. K. Brow, "XPS Characterization of In situ Prepared Ti/Glass Interfaces,"
        Surf. Interface Analyses, 24 113-118 (1996).

62.    R. K. Brow, L. Kovacic, and R. E. Loehman "Novel Glass Sealing Technologies," Proceedings of the International
        Symposium on Manufacturing Practices and Technologies, Ceramics Transactions, Vol. 50, 1996.

61.    R. K. Brow, "An XPS Study of Oxygen Bonding in Zinc Phosphate and Zinc Borophosphate Glasses," J. Non-Cryst.
        Solids, 194 267-273 (1996).

60.    R. K. Brow, D. R. Tallant, and G.L. Turner, "Raman and 11B NMR Spectroscopic Studies of Alkaline Earth
        Lanthanoborate Glasses," J. Amer. Ceram. Soc. 79[9] 2410-16 (1996).

59.    R. K. Brow and Z. A. Osborne, "XPS Studies of Fluorine Bonding In Phosphate Glasses," Surf. Interface Analyses,
        24 91-94 (1996).

58.    D. W. Schaefer, R. K. Brow, B. J. Olivier, T. Rieker, and G. Beaucage, "Characterization of Porosity in Ceramic
        Materials  by Small-Angle Scattering: Vycor Glass and Silica Aerogel," in Modern Aspects of Small-Angle Scattering,
        ed. H. Brumberger, pp. 299-307, Kluwer Academic Press, the Netherlands, (1995).

57.    R. K. Brow, D. R. Tallant, S. T. Myers, and C. C. Phifer, "The Short Range Structure of Zinc Phosphate Glass," J.
        Non-Cryst. Solids191 45-55 (1995).

56.    L. Kovacic, S. V. Crowder, R. K. Brow, and D. N. Bencoe, "Designing Aluminum Sealing Glasses for
        Manufacturability," Ceramic Transactions 50 95-108 (1995).

55.    X. J. Xu, D. E. Day, R. K. Brow, and P. M. Calahan, "Structure of tin fluorophosphate glasses containing PbO or
        B2O3," Phys. Chem. Glasses, 36[6] 264-271 (1995).

54.    D. L. Sidebottom, P. F. Green, and R. K. Brow, "Comparison of KWW and power law analyses of an ion-conducting
        glass," J. Non-Cryst. Solids 183 151-160 (1995).

53.    D. L. Sidebottom, P. F. Green, and R. K. Brow, "Anomalous Diffusion Model of Ionic Transport in Oxide Glasses,"
        Phys. Rev. B 51[5] 2770-76 (1995).

52.    D. L. Sidebottom, P. F. Green, and R. K. Brow, "Two Contributions to the ac Conductivity of Alkali Oxide Glasses,"
        Phys. Rev. Lett.74[25] 5068-5071 (1995).

51.    R. J. Kirkpatrick and R. K. Brow, "NMR Investigation of the Structures of Phosphate and Phosphate-Containing
        Glasses: A Review," Solid State Nuclear Magnetic Resonance, 5, 9-21 1995.

50.    R. K. Brow, C. M. Arens, X. Yu, and D. E. Day, "An XPS Study of Fe-Phosphate Glasses," Phys. Chem.
        Glasses, 35[3] 132-36 (1994).

49.    R. K. Brow, "Electron Beam Reduction of Sodium-Containing Glass Surfaces," J. Non-Cryst. Solids, 175 155-159
        (1994).

48.    P. F. Green, D. L. Sidebottom, and R. K. Brow, "Relaxations in Mixed Alkali Metaphosphate Glass," J. Non-Cryst.
        Solids, 172-174 1353-1362 (1994).

47.    R. K. Brow, D. R. Tallant, J. J. Hudgens, S. W. Martin, and A. D. Irwin, "The Short-Range Structure of Sodium
        Ultraphosphate Glasses," J. Non-Cryst. Solids 177 221-228 (1994).

46.    M. R. Reidmeyer, D. E. Day, and R. K. Brow, "Phosphorus Oxynitride Glasses of Variable Sodium Content," J.
        Non-Cryst. Solids 177 208-215 (1994).

45.    R. K. Brow, "The Nature of Alumina in Phosphate Glass I. Properties of Sodium Aluminophosphate Glass," J. Amer.
        Ceram. Soc. 76[4], 913-18 (1993).

44.    R. K. Brow, R. J. Kirkpatrick and G. L. Turner, "The Nature of Alumina in Phosphate Glass II. Structure of Sodium
        Aluminophosphate Glass," J. Amer. Ceram. Soc., 76[4] 919-28 (1993).

43.    R. K. Brow, "Inorganic Glasses and Glass-Ceramics," chapter 6 in Characterization of Ceramics, ed. R. E. Loehman,
        pp. 103-118, Butterworth-Heinemann, Stoneham, MA (1993).

42.    R. K. Brow, S. K. Saha, and J. I. Goldstein, "Interfacial Reactions Between Titanium and Borate Glass," Joining and
        Adhesion of Advanced Inorganic Materials, Proceedings of the Materials Research Society, Vol. 314, pp. 77-81
        (1993).

41.    R. K. Brow and H. L. McCollister, "Specialty Glass and Glass/Ceramic-to-Metal Seals," Materials Technology,
        8[11/12] 242-45 (1993).

40.    J. A. Kelber and R. K. Brow, "Model Epoxy/Metal-Oxide Chemical Interactions: Diethanolamine on Oxidized
        Copper and Aluminum," Applied Surface Science, 59, 273-280 (1992).

39.    R. K. Brow, C. C. Phifer, X. J. Xu and D. E. Day, "An XPS Study of Anion Bonding in Tin(II)-Fluorophosphate
        Glass," Phys. Chem. Glasses, 33[2], 33-39 (1992).

38.    R. K. Brow, Z. A. Osborne, and R. J. Kirkpatrick, "A Multinuclear MAS NMR Study of the Short-Range Structure of
        Fluorophosphate Glass," J. Materials Research, 7[7], 1892-99 (1992).

37.    R. K. Sato, R. J. Kirkpatrick, and R. K. Brow, "Structure of Li, Na Metaphosphate Glasses by 31P and 23Na MAS
        NMR Correlated with the Mixed Alkali Effect," J. Non- Crystalline Solids, 143 257-264 (1992).

36.    R. K. Brow, "Bonding in Simple Phosphate Glass," Proceedings of the XVIth International Congress on Glass, Vol.
        3, 191-196, Madrid, Spain, Oct. 4-9, 1992.

35.    R. K. Brow, D. R. Tallant, Z. A. Osborne, Y. Yang, and D. E. Day, "The Effect of Fluorine on the Structure of
        Phosphate Glass," Phys. Chem. Glasses, 32[5] 188-195 (1991).

34.    R. K. Brow, C. C. Phifer, G. L. Turner and R. J. Kirkpatrick, "Cation Effects on 31P Chemical Shifts of Metaphosphate
        Glasses," J. Amer. Ceram. Soc., 74 [6] 1287-90 (1991).

33.    G. A. Knorovsky, R. K. Brow, R. D. Watkins and R. E. Loehman, "Interactions at Glass-Ceramic/Metal Interfaces",
        in Glasses for Electronic Applications, Ceramic Transactions, Vol. 20, pp. 447-454, American Ceramic Society,
        1991.

32.    R. K. Brow, R. E. Loehman and A. P. Tomsia, "Reactive Metal Brazing of Aluminum Nitride," in Metal-Ceramic
        Joining, edited by P. Kumar and V. A. Greenhut, pp. 229-235, The Minerals, Metals Materials Society, 1991.

31.    G. A. Knorovsky, R. K. Brow, R. D. Watkins, and R. E. Loehman, "Interfacial Debonding in Stainless
        Steel/Glass-Ceramic Seals," in Metal-Ceramic Joining, edited by P. Kumar and V. A Greenhut, pp. 237-246, The
        Minerals, Metals & Materials Society," 1991.

30.    B. C. Bunker, R. J. Kirkpatrick, and R. K. Brow, "Local Structure of Alkaline-Earth Boroaluminate Crystals and
        Glasses: I, Crystal Chemical Concepts- Structural Predictions and Comparisons to Known Crystal Structures" J. Amer.
        Ceram. Soc., 74[6] 1425-29 (1991).

29.    B. C. Bunker, R. J. Kirkpatrick, R. K. Brow, G. L. Turner, and C. Nelson, "Local Structure of Alkaline-Earth
        Boroaluminate Crystals and Glasses: II, 11B and 27Al MAS NMR Spectroscopy of Alkaline-Earth Boroaluminate
        Glasses" J. Amer. Ceram. Soc., 74[6] 1430-38 (1991).

28.    C. J. Brinker, R. K. Brow, D. R. Tallant, and R. J. Kirkpatrick, "Surface Structure and Chemistry of High Surface Area
        Silica Gels," J. Non-Cryst. Solids, 120, 26-33 (1990).

27.    R. K. Brow, G. W. Arnold, Y. Zhu, and D. E. Day, "Surface Nitridation of a Phosphate Glass," J. Non-Cryst.
        Solids, 120, 172-177 (1990).

26.    G. W. Arnold, R. K. Brow, and D. R. Myers, "Characterization of the Near-Surface Region of Glass Implanted
        with Light Elements," J. Non-Cryst. Solids, 120, 234-240 (1990).

25.    G. W. Arnold, R. K. Brow, M. J. Carr, and J. C. Barbour, "Characterization of N and B Implanted Fused Silica,"
        Proc. Materials Research Soc., Vol. 157 569-74 (1990).

24.    R. K. Brow, R. J. Kirkpatrick, and G. L. Turner, "Local Structure of xAl2O3(1-x)NaPO3 Glasses: An NMR and XPS
        Study," J. Amer. Ceram. Soc., 73[8], 2293-2300 (1990).

23.    R. K. Brow, Y. Peng and D. E. Day, "Properties and Structure of P-O-N-H Glasses," J. Non-Cryst. Solids, 126,
        231-238  (1990).

22.    Z. A. Osborne, R. K. Brow and D. R. Tallant, "The Short-Range Structure of Fluorine-Modified Phosphate Glass," in
        Properties and Characteristics of Optical Glass II, Proceedings to the SPIE 1990 International Symposium on
        Optical and Optoelectronic Applied Science and Engineering, Vol. 1327, 203-211 (1990).

21.    R. K. Brow, R. J. Kirkpatrick, and G. L. Turner, "The Short Range Structure of Sodium Phosphate Glasses. I.
        MAS NMR Studies," J. Non-Cryst. Solids, 116, 39-45 (1990).

20.    R. K. Brow and R. E. Loehman, "Interfacial Reactions in Metal-Si3N4 Bonding," Ceram. Eng. Sci. Proc., [11-12],
        1685-1695 (1989).

19.    R. K. Brow, "Ion Beam Effects on the Composition and Structure of Glass Surfaces," J. Vac. Sci. Tech. A,
        7[4], 1673-1676 (1989).

18.    R. K. Brow, R. E. Loehman, A. P. Tomsia, and J. A. Pask, "Interface Interactions During Brazing of AlN," in Advances in
        Ceramics 26, Ceramic Substrates and Packages for Electronic Applications, ed. M. F. Yan, pp. 189-196, Amer. Ceram.
        Soc., Westerville, OH (1989).

17.    C. G. Pantano and R. K. Brow, "Hydrolysis Reactions at the Surface of Fluorozirconate Glass," J. Am. Ceram. Soc., 71[7],
        577- 581 (1988).

16.    R. K. Brow, "An XPS Study of YBa2Cu3Ox Surface Corrosion," in Ceramic Superconductors II, ed. M. F. Yan, pp.
        598-606, Amer. Ceram. Soc., Westerville, OH (1988).

15.    R. K. Brow, "Glass Surface Modifications During Ion Beam Sputtering," J. Non-Cryst. Solids, 107, 1-11 (1988).

14.    C. J. Brinker, R. K. Brow, D. R. Tallant, and R. J. Kirkpatrick, "Structure of Sol-Gel Silica," Mat. Res. Soc. Symp.
        Proc., Vol. 105, 289-294 (1988).

13.    R. K. Brow, M. R. Reidmeyer, and D. E. Day, "Oxygen Bonding in Nitrided Sodium- and Lithium-Metaphosphate
        Glasses," J. Non-Cryst. Solids, 99, 178-189 (1988).

12.    R. D. Watkins, L. Kovacic, P. R. Wengert, S. C. Douglas, R. K. Brow, S. N. Burchett, and H. K. Street, "Technology
        Transfer of CABAL-12 Glass to Support the Fabrication of the MC4050 Power Supply," Sandia Report SAND88-0498,
        Oct. 1988.

11.    R K. Brow and R. D. Watkins, "Reactions and Bonding Between Glasses and Titanium," in Technology of Glass,
        Ceramic, or Glass-Ceramic to Metal Sealing, ed. W. E. Moddeman, et al., pp. 25- 30, Winter Annual Meeting,
        Amer. Soc. Mech. Eng., Boston, MA, Dec. 13-18, 1987.

10.    R. D. Watkins, B. C. Bunker, S. C. Douglas, R. K. Brow, and E. E. Hellstrom, "Corrosion Resistant Glasses for Use in
        Lithium Ambient-Temperature Batteries," Proceedings of the 22nd Intersociety Energy Conversion Engineering Conference,
        pp. 1113-1118, Amer. Inst. Aeronaut. Astronaut., Philadelphia, PA, Aug. 10-14, 1987.

9.    C. G. Pantano, R. K. Brow, and L. A. Carman, "Oxynitride Thin Films from the Sol-Gel Process," in Sol-Gel Technology
        for Thin Films, Fibers, Preforms, Electronics, and Specialty Shapes ed. L. C. Klein, pp. 110-138, Noyes Publications,
        Park Ridge, NJ (1988).

8.    R. K. Brow, "Oxidation States of Chromium Dissolved in Glass Determined by X-Ray Photoelectron Spectroscopy
        (XPS)," J. Amer. Ceram. Soc., 70[5], C-129-C-131 (1987).

7.    R. K. Brow and C. G. Pantano, "Thermochemical Nitridation of Microporous Silica Films in Ammonia," J. Amer.
        Ceram. Soc., 70[1], 9-14 (1987).

6.    R. K. Brow and C. G. Pantano, "Compositionally Dependent Si2p Binding Energy Shifts in Silicon Oxynitride Thin
        Films," J. Amer. Ceram. Soc., 69[4], 314-316 (1986).

5.    R. K. Brow and C. G. Pantano, "Oxidation Resistant Sol-Gel Derived Silicon Oxynitride Thin Films," Appl. Phys.
        Lett., 48[1], 27-29 (1986).

4.    R. K. Brow and C. G. Pantano, "Composition and Chemical Structure of Nitrided Silica Gel," Mat. Res. Soc.
        Symp., Vol. 32, 361-367 (1984).

3.    C. G. Pantano, C. A. Houser, and R. K. Brow, "Chemical Analyses of Sol/Gel Surfaces and Thin Films," Mat. Res.
        Soc. Symp., Vol. 32, 255-266 (1984).

2.    R. K. Brow and C. G. Pantano, "Nitrogen Coordination in Oxynitride Glasses," J. Amer. Ceram. Soc., 67[4],
       C72-C74 (1984).

1.    R. K. Brow and W. C. LaCourse, "Fluorine Treatments of Soda-Lime Silicate Glass Surfaces," J. Amer. Ceram.
       Soc., 66 [8], C123-C124 (1983).
 

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